{"id":3275,"date":"2026-04-27T06:00:22","date_gmt":"2026-04-27T05:00:22","guid":{"rendered":"https:\/\/www.nanoworld.com\/blog\/?p=3275"},"modified":"2026-04-23T09:07:39","modified_gmt":"2026-04-23T08:07:39","slug":"fabrication-of-thin-film-composite-nanofiltration-membrane-employing-polyelectrolyte-and-metal-organic-framework-mof-via-spin-spray-assisted-layer-by-layer-assembly","status":"publish","type":"post","link":"https:\/\/www.nanoworld.com\/blog\/fabrication-of-thin-film-composite-nanofiltration-membrane-employing-polyelectrolyte-and-metal-organic-framework-mof-via-spin-spray-assisted-layer-by-layer-assembly\/","title":{"rendered":"Fabrication of Thin-Film Composite Nanofiltration Membrane Employing Polyelectrolyte and Metal\u2013Organic Framework (MOF) via Spin-Spray-Assisted Layer-by-Layer Assembly"},"content":{"rendered":"<p>Spin\u2011spray\u2011assisted layer\u2011by\u2011layer (LbL) assembly is an innovative technique for producing nanostructured thin films due to its rapid deposition and excellent substrate coverage. In this article, Farid Fadhillah fabricated a nanofiltration (NF) membrane composed of multilayers of polyethyleneimine (PEI) and poly(sodium\u20114\u2011styrene sulfonate) (PSS) on a polysulfone (PSF) support. The resulting membrane was subsequently coated with a metal\u2013organic framework (MOF303).<br \/>\nThe fabricated (PEI\/PSS)\u2085\u2013MOF303 membrane demonstrated a rejection rate of 18.94 \u00b1 1.58% and a permeability of 0.91 \u00b1 0.13 L\/(h\u00b7bar\u00b7m\u00b2), while also exhibiting improved antifouling performance. These findings highlight the potential of spin\u2011spray\u2011assisted LbL assembly as a promising route for thin\u2011film composite membrane fabrication.<br \/>\nSurface characterization was performed using a commercially available AFM system equipped with a <a href=\"https:\/\/www.nanoworld.com\/contact-mode-reflex-coated-afm-tip-arrow-contr\">NanoWorld Arrow\u2011CONTR AFM probe<\/a>, a silicon cantilever with a force constant of 0.2 N\/m, operated in contact mode. Lateral images were used to visualize surface inhomogeneities across the scanned region. The <a href=\"https:\/\/www.nanoworld.com\/contact-mode-reflex-coated-afm-tip-arrow-contr\">NanoWorld AFM probe<\/a> ensured stable tip\u2013sample interaction, enabling high\u2011quality topographical and lateral force mapping. This article emphasizes the importance of selecting a reliable AFM probe for nanoscale membrane characterization.<\/p>\n<figure id=\"attachment_3276\" aria-describedby=\"caption-attachment-3276\" style=\"width: 527px\" class=\"wp-caption alignnone\"><a href=\"https:\/\/dhipgo7nn2tea.cloudfront.net\/wp-content\/uploads\/2026\/04\/23090128\/NW0404.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-3276\" src=\"https:\/\/dhipgo7nn2tea.cloudfront.net\/wp-content\/uploads\/2026\/04\/23090128\/NW0404.jpg\" alt=\"4. Atomic Force Microscope image ((left): lateral retrace (scan size 100 \u00d7 100 \u03bcm), (right): particle size (scan size: 10 \u00d7 10 \u03bcm)).\" width=\"527\" height=\"250\" data-wp-pid=\"3276\" srcset=\"https:\/\/dhipgo7nn2tea.cloudfront.net\/wp-content\/uploads\/2026\/04\/23090128\/NW0404.jpg 527w, https:\/\/dhipgo7nn2tea.cloudfront.net\/wp-content\/uploads\/2026\/04\/23090128\/NW0404-300x142.jpg 300w\" sizes=\"auto, (max-width: 527px) 100vw, 527px\" \/><\/a><figcaption id=\"caption-attachment-3276\" class=\"wp-caption-text\">4. Atomic Force Microscope image ((left): lateral retrace (scan size 100 \u00d7 100 \u03bcm), (right): particle size (scan size: 10 \u00d7 10 \u03bcm)).<\/figcaption><\/figure>\n<p>Full Citation:<\/p>\n<p>Farid Fadhillah. Fabrication of Thin-Film Composite Nanofiltration Membrane Employing Polyelectrolyte and Metal\u2013Organic Framework (MOF) via Spin-Spray-Assisted Layer-by-Layer Assembly. Engineering Proceedings, 2025, 105(1). DOI: https:\/\/doi.org\/10.3390\/engproc2025105003<\/p>\n<p>Citing Licence<\/p>\n<p>This article is published under the Creative Commons Attribution (CC BY) license, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited. \u00a9 2025 by the author. Published by MDPI.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Spin\u2011spray\u2011assisted layer\u2011by\u2011layer (LbL) assembly is an innovative technique for producing nanostructured thin films due to its rapid deposition and excellent substrate coverage. In this article, Farid Fadhillah fabricated a nanofiltration (NF) membrane composed of multilayers of polyethyleneimine (PEI) and poly(sodium\u20114\u2011styrene sulfonate) (PSS) on a polysulfone (PSF) support. The resulting membrane was subsequently coated with a &hellip; <a href=\"https:\/\/www.nanoworld.com\/blog\/fabrication-of-thin-film-composite-nanofiltration-membrane-employing-polyelectrolyte-and-metal-organic-framework-mof-via-spin-spray-assisted-layer-by-layer-assembly\/\" class=\"more-link\">Continue reading <span class=\"screen-reader-text\" >Fabrication of Thin-Film Composite Nanofiltration Membrane Employing Polyelectrolyte and Metal\u2013Organic Framework (MOF) via Spin-Spray-Assisted Layer-by-Layer Assembly<\/span><\/a><\/p>\n","protected":false},"author":5,"featured_media":3276,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[3,1],"tags":[1044,62,66,65,228,242,17,1082,1084,1083,1038,1086,1085,425],"class_list":{"0":"post-3275","1":"post","2":"type-post","3":"status-publish","4":"format-standard","5":"has-post-thumbnail","6":"hentry","7":"category-news","8":"category-uncategorized","9":"tag-afmtips","10":"tag-afm-probes","11":"tag-afm","14":"tag-arrow-contr","15":"tag-atomic-force-microscopy","16":"tag-layer-by-layer","17":"tag-membrane","18":"tag-nanofiltration","19":"tag-nanoworld","20":"tag-reverse-osmosis","21":"tag-tfc","22":"tag-thin-films"},"_links":{"self":[{"href":"https:\/\/www.nanoworld.com\/blog\/wp-json\/wp\/v2\/posts\/3275","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.nanoworld.com\/blog\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.nanoworld.com\/blog\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.nanoworld.com\/blog\/wp-json\/wp\/v2\/users\/5"}],"replies":[{"embeddable":true,"href":"https:\/\/www.nanoworld.com\/blog\/wp-json\/wp\/v2\/comments?post=3275"}],"version-history":[{"count":5,"href":"https:\/\/www.nanoworld.com\/blog\/wp-json\/wp\/v2\/posts\/3275\/revisions"}],"predecessor-version":[{"id":3281,"href":"https:\/\/www.nanoworld.com\/blog\/wp-json\/wp\/v2\/posts\/3275\/revisions\/3281"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.nanoworld.com\/blog\/wp-json\/wp\/v2\/media\/3276"}],"wp:attachment":[{"href":"https:\/\/www.nanoworld.com\/blog\/wp-json\/wp\/v2\/media?parent=3275"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.nanoworld.com\/blog\/wp-json\/wp\/v2\/categories?post=3275"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.nanoworld.com\/blog\/wp-json\/wp\/v2\/tags?post=3275"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}