{"id":1098,"date":"2019-01-21T12:45:38","date_gmt":"2019-01-21T11:45:38","guid":{"rendered":"https:\/\/www.nanoworld.com\/blog\/?p=1098"},"modified":"2023-04-18T12:59:40","modified_gmt":"2023-04-18T11:59:40","slug":"self-assembled-pcbm-bilayers-on-graphene-and-hopg-examined-by-afm-and-stm","status":"publish","type":"post","link":"https:\/\/www.nanoworld.com\/blog\/self-assembled-pcbm-bilayers-on-graphene-and-hopg-examined-by-afm-and-stm\/","title":{"rendered":"Self-assembled PCBM bilayers on graphene and HOPG examined by AFM and STM"},"content":{"rendered":"<p>In the article \u00abSelf-assembled PCBM bilayers on graphene and HOPG examined by AFM and STM\u201d Yanlong Li, Chuanhui Chen, John Burton, Kyungwha Park, James R Heflin and Chenggang Tao demonstrate that PCBM molecules self-assemble into bilayer structures on graphene and HOPG substrates. They used Atomic Force Microscopy (AFM) and Scanning Tunneling Microscopy (STM), and analyzed the observed morphology by comparison to molecular models.*<\/p>\n<p>The AFM measurements were carried out in a dark environment. NanoWorld\u2122 <a href=\"https:\/\/www.nanoworld.com\/pointprobe-soft-tapping-mode-afm-tip-ncst\" target=\"_blank\" rel=\"noopener\">Pointprobe\u00ae NCST<\/a> AFM probes were used in soft tapping mode and simultaneous height and phase images were acquired and reproduced across multiple samples.*<\/p>\n<p>The results of this study shed light on improvement of the energy efficiency in solar cells containing graphene and organic molecules, by increasing the donor\u2013acceptor interface area and could provide valuable insight into fabrication of new hybrid, ordered structures for applications to organic solar cells.*<\/p>\n<figure id=\"attachment_1102\" aria-describedby=\"caption-attachment-1102\" style=\"width: 1570px\" class=\"wp-caption alignleft\"><a href=\"https:\/\/dhipgo7nn2tea.cloudfront.net\/wp-content\/uploads\/2019\/01\/21122254\/figure-5-from-Self-assembled-PCBM-bilayers-on-graphene-and-HOPG-examined-by-AFM-and-STM-_NanoWorld-NCST-AFM-probes-were-used.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-1102\" src=\"https:\/\/dhipgo7nn2tea.cloudfront.net\/wp-content\/uploads\/2019\/01\/21122254\/figure-5-from-Self-assembled-PCBM-bilayers-on-graphene-and-HOPG-examined-by-AFM-and-STM-_NanoWorld-NCST-AFM-probes-were-used.jpg\" alt=\"Figure 5. from \u201cSelf-assembled PCBM bilayers on graphene and HOPG examined by AFM and STM\u201d by Yanlong Li et al.: AFM images of PCBM bilayer and size distributions of holes at different conditions. (a) AFM image of a PCBM bilayer before annealing. (b) AFM image of a PCBM bilayer after annealing at 140 \u00b0C. (c) AFM image of a PCBM bilayer after annealing at 160 \u00b0C. (d) Area distribution histogram of holes (without PCBM area) obtained from measurements of the area of holes in AFM images of before (green) and after annealing at 140 \u00b0C (dark red) and 160 \u00b0C (dark blue). Monolithic silicon cantilevers (NCST, NANO WORLD) with a spring constant of 7.4 N m\u22121, first longitudinal resonance frequencies between 120 and 205 kHz, and nominal tip radius of 8 nm were employed in soft tapping mode. Simultaneous height and phase images were acquired and reproduced across multiple samples.\" width=\"1570\" height=\"1240\" data-wp-pid=\"1102\" srcset=\"https:\/\/dhipgo7nn2tea.cloudfront.net\/wp-content\/uploads\/2019\/01\/21122254\/figure-5-from-Self-assembled-PCBM-bilayers-on-graphene-and-HOPG-examined-by-AFM-and-STM-_NanoWorld-NCST-AFM-probes-were-used.jpg 1570w, https:\/\/dhipgo7nn2tea.cloudfront.net\/wp-content\/uploads\/2019\/01\/21122254\/figure-5-from-Self-assembled-PCBM-bilayers-on-graphene-and-HOPG-examined-by-AFM-and-STM-_NanoWorld-NCST-AFM-probes-were-used-300x237.jpg 300w, https:\/\/dhipgo7nn2tea.cloudfront.net\/wp-content\/uploads\/2019\/01\/21122254\/figure-5-from-Self-assembled-PCBM-bilayers-on-graphene-and-HOPG-examined-by-AFM-and-STM-_NanoWorld-NCST-AFM-probes-were-used-768x607.jpg 768w, https:\/\/dhipgo7nn2tea.cloudfront.net\/wp-content\/uploads\/2019\/01\/21122254\/figure-5-from-Self-assembled-PCBM-bilayers-on-graphene-and-HOPG-examined-by-AFM-and-STM-_NanoWorld-NCST-AFM-probes-were-used-1024x809.jpg 1024w, https:\/\/dhipgo7nn2tea.cloudfront.net\/wp-content\/uploads\/2019\/01\/21122254\/figure-5-from-Self-assembled-PCBM-bilayers-on-graphene-and-HOPG-examined-by-AFM-and-STM-_NanoWorld-NCST-AFM-probes-were-used-1200x948.jpg 1200w, https:\/\/dhipgo7nn2tea.cloudfront.net\/wp-content\/uploads\/2019\/01\/21122254\/figure-5-from-Self-assembled-PCBM-bilayers-on-graphene-and-HOPG-examined-by-AFM-and-STM-_NanoWorld-NCST-AFM-probes-were-used-800x632.jpg 800w, https:\/\/dhipgo7nn2tea.cloudfront.net\/wp-content\/uploads\/2019\/01\/21122254\/figure-5-from-Self-assembled-PCBM-bilayers-on-graphene-and-HOPG-examined-by-AFM-and-STM-_NanoWorld-NCST-AFM-probes-were-used-798x630.jpg 798w, https:\/\/dhipgo7nn2tea.cloudfront.net\/wp-content\/uploads\/2019\/01\/21122254\/figure-5-from-Self-assembled-PCBM-bilayers-on-graphene-and-HOPG-examined-by-AFM-and-STM-_NanoWorld-NCST-AFM-probes-were-used-794x627.jpg 794w\" sizes=\"auto, (max-width: 1570px) 100vw, 1570px\" \/><\/a><figcaption id=\"caption-attachment-1102\" class=\"wp-caption-text\">Figure 5. from \u201cSelf-assembled PCBM bilayers on graphene and HOPG examined by AFM and STM\u201d by Yanlong Li et al.: AFM images of PCBM bilayer and size distributions of holes at different conditions. (a) AFM image of a PCBM bilayer before annealing. (b) AFM image of a PCBM bilayer after annealing at 140 \u00b0C. (c) AFM image of a PCBM bilayer after annealing at 160 \u00b0C. (d) Area distribution histogram of holes (without PCBM area) obtained from measurements of the area of holes in AFM images of before (green) and after annealing at 140 \u00b0C (dark red) and 160 \u00b0C (dark blue).<\/figcaption><\/figure>\n<p>*Yanlong Li, Chuanhui Chen, John Burton, Kyungwha Park, James R Heflin, Chenggang Tao<br \/>\nSelf-assembled PCBM bilayers on graphene and HOPG examined by AFM and STM<br \/>\nNanotechnology, Volume 29, Number 18 (2018)<br \/>\nDOI: <a href=\"https:\/\/doi.org\/10.1088\/1361-6528\/aab00a\" target=\"_blank\" rel=\"noopener\">https:\/\/doi.org\/10.1088\/1361-6528\/aab00a<\/a><\/p>\n<p><b>Open Access<\/b> The article \u201cSelf-assembled PCBM bilayers on graphene and HOPG examined by AFM and STM\u201d by Yanlong Li et al. is licensed under a Creative Commons Attribution 3.0 International License. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI. To view a copy of this license, visit <a href=\"https:\/\/creativecommons.org\/licenses\/by\/3.0\/\" target=\"_blank\" rel=\"noopener\">https:\/\/creativecommons.org\/licenses\/by\/3.0\/ <\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>In the article \u00abSelf-assembled PCBM bilayers on graphene and HOPG examined by AFM and STM\u201d Yanlong Li, Chuanhui Chen, John Burton, Kyungwha Park, James R Heflin and Chenggang Tao demonstrate that PCBM molecules self-assemble into bilayer structures on graphene and HOPG substrates. They used Atomic Force Microscopy (AFM) and Scanning Tunneling Microscopy (STM), and analyzed &hellip; <a href=\"https:\/\/www.nanoworld.com\/blog\/self-assembled-pcbm-bilayers-on-graphene-and-hopg-examined-by-afm-and-stm\/\" class=\"more-link\">Continue reading <span class=\"screen-reader-text\" >Self-assembled PCBM bilayers on graphene and HOPG examined by AFM and STM<\/span><\/a><\/p>\n","protected":false},"author":3,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[3],"tags":[150,149,62,17,145,76,151,147,146,152,38,16,89,110,13,148],"class_list":["post-1098","post","type-post","status-publish","format-standard","hentry","category-news","tag-2d-material-hybrid-solar-cells","tag-2d-materials","tag-afm-probes","tag-atomic-force-microscopy","tag-ncst","tag-non-contact-afm","tag-organic-hybrid-solar-cells","tag-organic-solar-cells","tag-pcbm","tag-phenyl-c61-butyric-acid-methyl-ester","tag-pointprobe","tag-scanning-probe-microscopy","tag-soft-tapping-mode","tag-solar-cell","tag-spm-probes","tag-two-dimensional-materials"],"_links":{"self":[{"href":"https:\/\/www.nanoworld.com\/blog\/wp-json\/wp\/v2\/posts\/1098","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.nanoworld.com\/blog\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.nanoworld.com\/blog\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.nanoworld.com\/blog\/wp-json\/wp\/v2\/users\/3"}],"replies":[{"embeddable":true,"href":"https:\/\/www.nanoworld.com\/blog\/wp-json\/wp\/v2\/comments?post=1098"}],"version-history":[{"count":6,"href":"https:\/\/www.nanoworld.com\/blog\/wp-json\/wp\/v2\/posts\/1098\/revisions"}],"predecessor-version":[{"id":1105,"href":"https:\/\/www.nanoworld.com\/blog\/wp-json\/wp\/v2\/posts\/1098\/revisions\/1105"}],"wp:attachment":[{"href":"https:\/\/www.nanoworld.com\/blog\/wp-json\/wp\/v2\/media?parent=1098"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.nanoworld.com\/blog\/wp-json\/wp\/v2\/categories?post=1098"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.nanoworld.com\/blog\/wp-json\/wp\/v2\/tags?post=1098"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}